SLO 3.4 Molecular Structure
Students will predict molecular geometry based on VSEPR and valence bond theory paradigms
Key Concepts and Skills
- Electron Geometry: Use valence shell electron pair repulsion (VSEPR) theory to predict the electron geometry of molecules, and their bond angles.
- Molecular Geometry (Shape): Assign molecular geometries to compounds from a symbolic representation (formula, Lewis structure) using VSEPR. Determine bond angles including describing why deviations from ideal bond angles occur.
- Hybridization and Valence Bond Theory: Demonstrate how hybrid orbitals are formed for atoms in a molecule using and describe the resulting orbital shape for \(sp\), \(sp^2\) and \(sp^3\). Connect hybridized geometries to the conclusions derived from VSEPR.
- Pi and Sigma Bonding, Identify molecular bonds as pi (\(\pi\)) or sigma (\(\sigma\)), explain properties of pi and sigma bonds, and explain how orbital overlap leads to different bond types.
- Polar Molecules: Identify polar molecules by determining appropriate partial charges (sign and magnitude) of an atom and assess magnitude and direction of individual bond and molecular dipole moments.
Reading
- From the textbook:
- 11.2: VSEPR Theory: The Five Basic Shapes
- 11.3: VSEPR Theory: The Effect of Lone Pairs
- 11.4: VSEPR Theory: Predicting Molecular Geometries
- 11.5: Molecular Shape and Polarity
- 11.6: Valence Bond Theory: Orbital Overlap as a Chemical Bond
- 11.7: Valence Bond Theory: Hybridization of Atomic Orbitals
- POGIL Activities
- CA-17: What Shapes Do Molecules Have?
- CA-H: What Does an Electron Do in a Chemical Bond?
- Other:
Important Terms
VSEPR Theory | Valence Bond Theory |
Electron Domains | Atomic Orbital |
Bonding Domains | \(\sigma\) Bonding |
Nonbonding Domains | \(\pi\) Bonding |
Tetrahedral Geometry | Orbital Hybridization |
Trigonal Planar Geometry | Bond Dipole |
Linear Geometry | Molecular Dipole |
Sample Assessment Questions
Dr. Thompson Videos
-
Valence Bond Theory - \(\sigma\) and \(\pi\) bonding
-
Valence Bond Theory - Bonding Part 1?
-
Valence Bond Theory - Bonding Part 2?
-
Valence Bond Theory - Quick Bonding Overview
-
Valence Bond Theory - Hybridization
External Videos, Tutorials, Simulations
- Molecular Shapes
- Hybridization
- Crash Course Chemistry - Hybridization
- Khan Academy - Valence Bond Theory
- Khan Academy - pi Bonding
- Crash Course Chemistry - Covalent Bonding
- Crash Course Chemistry - Polarity
- PhET - Molecular Shapes
- PhET - Polarity
Practice Problems
- From the textbook:
- 11.7, 11.14, 11.27, 11.31-32, 11.45-48, 11.53-56, 11.61-62, 11.83, 11.85
- From other external sources:
- From Dr. Thompson (links and embedded versions below):